No, they're not rectified. Nor would you need a diode or cap. Only when using a DC relay should you use a diode. The purpose of the diode is to capture the inductive kickback when DC drops out. The drawing I gave you is horribly basic, but accurate nonetheless. As for voltage sensing - with brown-outs (when power drops but doesn't go completely out) the relay may or may not drop out and switch on the emergency lights. It's been years since I've seen emergency lighting systems but that's pretty basic - power drops completely and the lights come on. In America the standard is that the lights should burn for a minimum of 90 minutes providing sufficient light for someone to find the exit. As for UK standards - I can say nothing on that subject.Are AC coils rectified (I've assumed a diode and a smoothing capacitor)?
Having a transistorized switching system is possible (I would imagine). Would have to give it some thought, but I don't really feel so inclined to do so. Sorry, I'm too busy flying about these days trying to get a business of my own up and running.
