Mplabx ide lists that pic. It is programmable by the pickit3. I want to use the 32khz crystal as timer 1 or the secondary oscillator if I am correct.When you chose the PIC16F15313 did you check that you could program it using MPLAB and the PICKIT3 ?
If you can't program it there is no point in anyone writing code to run on the PIC16F15313.
Also the normal 16 Mhz crystal will probably only be accurate to about 20 PPM and you said that you want 0.2 PPM .
Les.