Here is the circuit in question.

So, any component adjacent to a battery source will have the polarity of the battery.

What determines the polarity of R2? The negative source is greater, but does the voltage drops across R1 and R3 have any affect on the polarity of R2? It is neccesary for calculating the simultaneous KCL equations to determine current. I know that it is positive toward ground but how is that determined?

So, any component adjacent to a battery source will have the polarity of the battery.

What determines the polarity of R2? The negative source is greater, but does the voltage drops across R1 and R3 have any affect on the polarity of R2? It is neccesary for calculating the simultaneous KCL equations to determine current. I know that it is positive toward ground but how is that determined?
