I showed you why your numbers are mixed up. It is the same for PNP and NPN transistors. This is for an NPN transistor:Numbers are OK.
Only for PNP Vec is 0.6V greater then Veb
For NPN Vec is smaller then Veb.
If you don't believe my measurements do the measurement yourself.
1) The reverse-biased emitter-base breakdown voltage is 6.0V.
2) The forward biased collector-base junction voltage is 0.65V.
3) The total of the two voltages is 6.65V because they are in series.
Some of your collector-base junction voltages are wrong because they are 1.5V instead of 0.65V.