That was used for protects the ADC and the Vzd should be a little higher than V_R2, add it or not that it is depends on you.1. Zener diode on the second circuit of with comparator:
By the way the zener diode should still not be there on your second circuit with the OPAMP, on post #24 I think.
2. Capacitor on the ADC pin:
You mean that to adds a 0.1uF across on R2 for filtering the noise?Should I put a cap for filtering the noise and how much should it be?