My plan on this, as a first cut, is to model the container in a very simple way: basically as a nearly rigid barrier, or as close as I can get to that in a numerical simulation. So basically, this would look like a spherically symmetric very high potential barrier. Of course, I realize that this is completely unrealistic. Not only is there the issue that the structure would be made of atoms, but the surface roughness in a real container is far from a sphere at the molecular level. But, I figure one has to start somewhere.I mean whatever keeps the electrons from moving further and further apart by simply expanding the (outer) shell. So yes I mean the 'container' if you like.
I'm open to any suggestion, either now or after I put forth some documentation. Either way, I wouldn't use this suggestion until a second pass at refining the calculations. I just feel I need to walk (or even crawl) before i try to run.
Speaking of this issue of realism versus simplicity; last night I faced another case where I decided on simplicity as a first cut. In doing any kind of a dynamic calculation, used as a way to find the stable static solutions, we run into the need to have dissipation in the system. In a conductor, this is somewhat easy since we can make the approximation of using Ohms law as a form of heat dissipation. In this case, we don't have that ability. A realistic model would need to consider electromagnetic radiation due to accelerating electrons, and dissipation processes as electrons hit the walls, and probably some other things I can't think of right now. However, this is getting much too complicated for my purpose. A simple velocity dependent friction term is all I need to use, to get the electrons to damp down to a stable state. Again, the idea is to crawl first, then maybe run later.
As always, you bring up good points.
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