Hey Steve,
With all due respect, I do know Gauss' law. And what it tells us is that the flux through a surface is proportional to the charge contained within. There are some consequences to this, but that all charges within a spherical surface having to be in a in a single, one electron thick, layer is not one of them.
We can have equilibrium in a multilayer case when the force required to place an electron in the outermost layer exceeds the force driving it there. As you pointed out, once we have a sufficient charge density in the outer layer, there is no field within that layer to drive a single electron anywhere. Adding a second electron in that cavity will then provide a mutual repulsion that will force the electrons to the outer shell. Once they get there and get arbitrarily close to the charges there, there will be a potential barrier for them to overcome in order to actually be a part of that shell. That potential is related to driving the existing charges closer together. As the charge density in that outer layer increases so does the potential required to insert another electron. At some point it will be high enough that a small number of electrons will not be able to mutually generate the force required to enter it. As a result, as more electrons are added, not only does the second layer get more populated, but so does the outer one.
If this continues, you will eventually distribute electrons throughout the interior of the sphere.
BTW, I only brought QM into my post to mention it was not significant
With all due respect, I do know Gauss' law. And what it tells us is that the flux through a surface is proportional to the charge contained within. There are some consequences to this, but that all charges within a spherical surface having to be in a in a single, one electron thick, layer is not one of them.
We can have equilibrium in a multilayer case when the force required to place an electron in the outermost layer exceeds the force driving it there. As you pointed out, once we have a sufficient charge density in the outer layer, there is no field within that layer to drive a single electron anywhere. Adding a second electron in that cavity will then provide a mutual repulsion that will force the electrons to the outer shell. Once they get there and get arbitrarily close to the charges there, there will be a potential barrier for them to overcome in order to actually be a part of that shell. That potential is related to driving the existing charges closer together. As the charge density in that outer layer increases so does the potential required to insert another electron. At some point it will be high enough that a small number of electrons will not be able to mutually generate the force required to enter it. As a result, as more electrons are added, not only does the second layer get more populated, but so does the outer one.
If this continues, you will eventually distribute electrons throughout the interior of the sphere.
BTW, I only brought QM into my post to mention it was not significant