The plasma is normally at a positive potential (electrons have a higher thermal velocity) relative to any surface due to plasma electron loss with Capacitive RF drive systems. With a Inductive RF process reactor the sheath potentials in the plasma are usually lower. The impedance is a factor of Debye_length, the Plasma Sheath (their impedance will vary with the applied RF current) formed from that layer with a positive space charge, the physical dimensions (area, spacing) of the chamber, gas type, pressure, flow and many other factors. It's usually lower than a typical generator impedance of 50 ohms so a match that adjusts to chamber conditions will be needed