Something very odd is going on if the schematic actually matches the physical circuit.
When the power switch is ON (in AC position), C21 (hidden by terminal strip) should be around 29 volts (as you measured at DC power input jack) and C22 should be around 24 volts. With the switch in the OFF position and with no external DC supply, both capacitors should drop slowly to some low voltage, and eventually to zero.
What you have observed makes no sense. How C22 gets to normal operating voltage with the switch in the DC position then decays to zero in the AC position is beyond my understanding. I'm assuming you aren't using an external DC supply, since I didn't see one mentioned.
When the power switch is ON (in AC position), C21 (hidden by terminal strip) should be around 29 volts (as you measured at DC power input jack) and C22 should be around 24 volts. With the switch in the OFF position and with no external DC supply, both capacitors should drop slowly to some low voltage, and eventually to zero.
What you have observed makes no sense. How C22 gets to normal operating voltage with the switch in the DC position then decays to zero in the AC position is beyond my understanding. I'm assuming you aren't using an external DC supply, since I didn't see one mentioned.