While you are waiting for an answer from someone who actually knows about this:
I've never used Pic's but from what I read and seen from this guy :
http://www.youtube.com/watch?v=LjfIS65mwn8
The Pickit3 is just a newer version of the Pickit2 . I actually wanted to start with Pics but my local store didn't have pic kit 2 , they had pickit3 and that came with a prototype board and alltogether cost 100euro versus the 40 euro for the AVRISPmkii so I started with AVR
I've never used Pic's but from what I read and seen from this guy :
http://www.youtube.com/watch?v=LjfIS65mwn8
The Pickit3 is just a newer version of the Pickit2 . I actually wanted to start with Pics but my local store didn't have pic kit 2 , they had pickit3 and that came with a prototype board and alltogether cost 100euro versus the 40 euro for the AVRISPmkii so I started with AVR