That is a confusing question.if resistor is E12 (10%) and 4th band is gold( 5%) then what is the actual value of 100 Ohms resistor
the E12 standard says value of 100 Ohms resistor 90 to 110 then what is the 5%
If the 4th band is gold (5%) then the value very likely is one from the E24 chart, but does not have to be.
A 100Ω 5% resistor has a value of 100Ω with ±5% tolerance.
In today's manufacturing process, resistors are made with tight process control. They are not measured and selected. Hence the statistical distribution fits a bell curve. The probability of finding a resistance value that deviates from its nominal value diminishes as the value moves away from the nominal value.

