Let's wait for the TS to respond. My impression from his first post was that he wanted to use one LED. Using an optocoupler rather a phototransistor is a bit of a moot point to me. Using a photocell or LDR is not quite the same. My point was and is that simply monitoring one LED is not likely to work well.I think he planning on using more than one photo(device); one per LED was my impression. And not opening or tampering with the device was my impression. I've rolled my own photocoupler in the past by putting a LED and a photodiode together end-to-end inside a heat shrink tube. Without opening the case, just glueing/taping photo-somethings to the case, it might present a small challenge to detect whether an LED is actually on, or if the one next to it is on - there will be some "cross-talk." So it may make more sense to use photoresistors connected to a level detector. This would be super simple to do inside an arduino using analog inputs and empirically derived values to differentiate between LED-ON and LED-(neighbor)-ON (OFF).
Using an arduino or similar uC, it would be trivial to program in recognition of all these binary states and unique actions for each/any of interest.