Ok. A couple of things wrong here.6.8V dc at one side of R199 0V dc at the other side of R199 in ON
and 8.2V dc on one side of R199 and 0V dc in standby
0V dc at both sides of R188 in standby and ON.
R199 appears to be blown open. Measure the resistance of R199. 10Ω expected.
D131 could be blown shorted.
Q137 could be blown. Not sure as yet. Still need investigating.
POWER_RLY from IC101 pin-26 to R188 does not seem correct on ON mode.
Edit: I just read your correction in post #20. That makes a huge difference now.