May be missing some thing in all of this. But isn't AC coming from the mains through a step down transformer going to be just as dangerous as the same voltage coming from your converter? But the step down transformer will have a much better/accurate sine wave.
If you do something dumb like latch yourself across both leads of the secondary or there is leakage to ground then your statement is probably true. But otherwise a transformer will be safer due to isolation from earth ground.