Not possible, of course.
Looks like a typo, as it lists a standard germanium junction diode, but the description is for a silicon Schottky barrier diode.
A metal to germainum junction would be a Schottky diode, which is what I believe the original 1N60 and the 1N34 (among many others) were but the datasheet says "Metal silicon junction..."
I think so. Hold an old 1N34 up to the light and you can see a little wire going from one lead to the bit of germanium. I cannot confirm this, as I said "I believe..."
BUT then in a Wikipedia entry it says:
A pointed metal wire is placed in contact with an n-type semiconductor. Some metal migrates into the semiconductor to make a small p-type region around the contact.