Yes, meters read average or RMS, most likely I am confused, I was going with your simulation result of -325V peak.Your meter will read average DC or rms.
If it reads average DC then the average will be peak/(2√2) =115V
If you connect between S2 and mains live, you will also get a half-wave signal, the same as if you connect between S2 and neutral.
I still think that the opto pin1 should go to neutral.
I am tempted to try Pin 1 to neutral...