Thank you @atferrari, nice to speak with a rope expert. I definitely won't use hemp. It will be either 1/4-inch poly rope or zip ties. I watched the video you linked, and the hot knife option is along the same lines as I am thinking, but a homemade version. If she doesn't have a heat source, I thought using the battery to heat the knife/wire would work instead of a flame.@Triple9Nickel
Worked my whole life in an environment where ropes are of daily use to lift and secure things even big vessels. Personally I even did splices and other traditional labors with them.
In the past, hemp was the rule; hard to handle (heavy and rigid) is a rough material which becomes easily hardened when wet. Do not allow the bad guys to tie your heroine with that! She will hate you for the rest of the story. And maybe even after... She will have to burn herself to burn the ropes. Bad business.
Fibers, light as they are, even the old nylon or polyethylene, dacron, perlon, etc. are really strong (that's why they are used for that, after all). Just for you to understand what she could face please note that what this guy has to use for cutting the rope. Add to that if your bad guys are good professionals would tie her with the arms on her back. Expect a mess.
My suggestion: provide the bad guys (police also use them) with enough zip ties and convince her to carry a (metallic) big size nail file, starting in Chapter 4, just in case plans change without notice.
Otherwise...