I don't think that's an issue here. OP gets the sunlight for free. Inefficiency just means it takes longer to charge, but it's still free. The general recommendation has been to find a lot of solar cells and wire them appropriately to get current/voltage for requirements.One thing to note about Solar is that it's usually less than 10% efficient, even with Fresnal lenses. You may want to look at other options as well (to combine with a solar station) such as wind or even a Peltier device.
Don't think she'll have much luck scrounging Peltier junctions in the trash; and their efficiency is in the same ballpark as solar cells.