Indeed.Thank you everyone for your comments. I hadn't considered that a square wave would give a different perceived effect than a sine wave which would illuminate the LED for a shorter period at the same frequency.
It's why Ton and Toff are important factors in many applications where frequency becomes less important.
Example, PWM for LED control vs PWM for motor control. The latter does have a liking for specific frequency, whereas LED's (for light) not so much.
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