Definitely yes. I was working on a TV and the horizontal output tube had a top terminal and the plastic cap was cracked. The arc burnt a nice row of holes in my hand as I jerked it out of the way. The only ground on me was the capacitance to the planet through the soles of my shoes.I don't have enough capacitance to notice much at 230V 50Hz - but several kV at TV horizontal frequency is a different matter.
