Ah! ... so a pFet would be a better choice then? ... I have a few DMP2066LSN with me that I could use. Thanks for the suggestion.Doesn't make any difference. Current will still flow from the +6V battery through R1 into the upper ESD protection diode of the PIC's ADC input.
If you want to prevent that, you need a high-side switch between the battery and your voltage divider, not a low-side switch between the divider and ground.