Thank you for the answer, BR-549.I believe your assumption is incorrect.
When you connect a long wire to the negative terminal of a battery, the wire is only polarized.....there is no charge transfer.
The reason that there is no charge transfer is because of the positive pole. The positive pole keeps the same number of electrons on the negative pole.
If you touch the wire to a mono-pole charge.......i.e.......a charged balloon or a charged sphere......then you can charge the wire.
Polarization of the wire would redistribute the free electrons along the wire. Thus the density of the electrons would be lower at the end attached to the battery, and it would be higher at the opposite end.
This brings another question: why the potential difference between any point of the wire and the positive terminus of the battery be about exactly the same?
Also, can you please support your answer with formulas or references or prove it any other way?