Better to consider that the micro's analog inputs will be saturated when you get to the full scale of the ADC. And keep in mind that a 3.3V reference (supply?) has a tolerance, and could be some percentage lower than 3.3V. Scale your input to not exceed maybe only 90% of that lowest reference value.... should I make the voltage divider values for R18 and R19 27K and 100K so the signal is 3.3V with ... the battery is fully charged to 4.2V...