I figured if I got a wall psu with a higher voltage, say 14v, then it would take priority to the load due to the diode ORing. The chargers "inputs" are parallel to the 14v, so i figured while plugged into the wall, that the 14v would power the load since it would be higher than the battery voltage and the 14v would power the charger. When the 14v is unplugged, then the battery will power the load.You have more variables consider.
You have 3 different voltages to contend with. Your 12V adapter, your "12V" charger (which you've stated has a higher voltage), and the battery voltage. As you've wired them in your latest drawing, you have the charger and PSU fighting each other. You didn't have that problem in your original drawing because the jack was only allowing the adapter or battery/charger to be in-circuit. Your diagram isn't correct anyway. The charger would be across the battery terminals and with the diodes, there would be no conflict.
Then you need to deal with the situation where the PSU is off. Will you just unplug it from the outlet or will you physically disconnect it?
Finally, you need to address the situation where the charger is charging the battery and the circuit is being operated from the battery. The circuit draws more current than the charger can provide, so it can't charge the battery and power the circuit at the same time. It's also unclear whether your circuit would tolerate the charging voltage.
I guess my thinking was incorrect. Lol ill have to try again. Haha