I think you need to revise your section. It is wasteful to use a reverse parallel diode to shunt voltage around the LED. In this case, we are dealing with 354Vpk AC. The ballast resistor is going to have to dissipate that negative shunt IR loss ...despicable.To the other people trying to help, please read the AAC book chapter I recommended before trying to help. You are confusing the issue without researching the background.
The back-to-back 25 LED idea is more reasonable, but runs into reverse polarity protection problems (5Vreverse x 25) + (3V fwd x 25) = 225V which is not enough to protect against 354VACpk. Or, if they are a 25 series-parallel arrangement then each leg would still need a series protection diode.
Consider that 50 LEDS in series is 50 x 3V = 150V (forward voltage) and that 250VAC x 1.414 = 354VACpk. That means the diodes will conduct during the (positive) 150VAC to 354VAC range -- that's ~200V. Who's saying that's not enough or it won't work?
By using a series diode (1N4007 or such) to protect against reverse conduction, which manifests as a half-wave rectifier, the ballast resistor only needs to dissipate the remaining IR drop (the negative half is eliminated). Note that creating a smoothed DC with a filter cap is NOT necessary.
Although the PRF of the half-wave is 50 Hz, the effect is similar to 25Hz or so because the LEDS are only on during the +150V to +354V region. That's a lot of off time, but in this case it shouldn't matter.
However, I don't think messing directly with 250VAC is the best, or safest, way to do this. Using a step-down transformer and connecting the LED's in parallel or series-parallel would be a better approach.
Regardless, see attached:
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