For the risetime,you measure the time interval between when the rising voltage is at 10% of its final value till it is at 90% of its final value.
Fall times are,logically, measured from 90% to 10%.
The idea is to ignore any artifacts around the start & finish of the rise or fall.
Tilt is measured by setting the amplitude between 0 volts (the baseline) & the maximum amplitude of the waveform as 100%,then measuring the difference between max & min levels of the flat top in %.
Obviously,the waveform must have a nominally flat top of a reasonable duration.
Any artifacts just after the rise,or just before the fall are ignored.