The PIC32 is an extremely impressive series of uCs. They are giving ARM a run for their money, though a bit late to the game. The beauty of it is they are programmed using the same PICKit 2 or 3 (mostly 3) that is used to program the 8 bit PICs with.Have you seen this: http://geoffg.net/maximite.html ?
The guy has made like an old Apple computer using a gawd dam PIC!