I don't mean to be contradictory, but I don't think this is true. I regularly use a capacitive transformer that limits CURRENT (1 amp or so.) A heavily sulfated battery can often be revived by applying 120VDC (not a typo) to it. No damage happens at all. (Although dealing with those voltages, utmost care must be taken as handling mistakes could be lethal.) As is the case with most electrochemical reactions, the cells will only rise to the voltage needed to pass current. As the voltage across the cells drops, the current rises (which is why current needs to be limited, or it would certainly damage it.) The higher voltage can overcome the sulfation resistance and start moving current, breaking up the sulfation.It's not exactly safe to charge at 16v since that would be like forcing an enormous amount of power all at once. However, that depends on how many amps your charger is. If it can charge it without dropping much in voltage then it would be charging too fast, which would eventually cause the battery to get extremely hot resulting in a dangerous environment.
As stated before put a separate load (resistor/light bulb/etc) in series with the battery and charger to draw some of the current away so it will not stress the battery as much. Most 12v lead acid batteries fully charge around 14.4v anyway.
Maybe not always, for example in the case you note where the battery has extremely high internal resistance. But it is certainly true for the normal case of a well-maintained battery. And even in the case you noted, the charger quickly drops into current-regulation mode once the hurdle is overcome....I don't think this is true...
Completely agree! My point was not well stated. The point: CURRENT is actually more important than voltage above the point that allows current to flow. Moderating the voltage supplied in a normal battery is one way of limiting current. The lower voltage (say 13.2V) reduces current flow significantly. (Floats)Maybe not always, for example in the case you note where the battery has extremely high internal resistance. But it is certainly true for the normal case of a well-maintained battery. And even in the case you noted, the charger quickly drops into current-regulation mode once the hurdle is overcome.
Charging a 12V battery with unlimited current at 16V would be a very bad idea.
by Duane Benson
by Jake Hertz