Ion flow and current

Thread Starter

jpanhalt

Joined Jan 18, 2008
11,087
Current requires electrical charges to move, not neccessarily electrons" so is that correct. As an example. The current flow in the human body is due to ion flow, not electrons.
Any comments?

John
 

Wendy

Joined Mar 24, 2008
23,429
So I wonder how the current got there.

The other thought is, discounting chemical reactions, the remaining majority current is electrons.

There are other electrochemical types of current (notably batteries), but when it hits a wire or conventional conductor it is all electrons.

Lets take an example that isn't quite as obvious though, water and table salt. There is electrolysis going on there, but there is also straight forward conduction. Does this mean most of the current is not electrons? I've never really thought about it, my instinct says it is electrons too. I remember my physics class in college measuring the electric field in diluted water.

Pure water is not a conductor, not even a poor one. I've serviced high power lasers that used DI water to cool xenon flash tubes that were continuously fired with 350VDC at quite a few amps, all the current went through the xenon tube, not the water.
 

Wendy

Joined Mar 24, 2008
23,429
Just googling around...

http://everyday-chemistry.suite101.com/article.cfm/does_distilled_water_conduct_electricity

Wikipedia's take on the subject...
http://en.wikipedia.org/wiki/Ion_flow

One paragraph I found interesting, and am not sure I believe, in the article...

In metallic solids, electricity flows by means of electrons, from higher to lower electrical potential. In other media, any stream of charged objects may constitute an electric current. So when there is higher cross sectional area there is less resistance. Conventional currents flows in the opposite way of electron current. In terms of Ohm's law current is proportional to voltage and inversely proportional to the resistance.
In a vacuum, a beam of ions or electrons may be formed. In other conductive materials, the electric current is due to the flow of both positively and negatively charged particles at the same time. In still others, the current is entirely due to positive charge flow. For example, the electric currents in electrolytes are flows of electrically charged atoms (ions), which exist in both positive and negative varieties. In a common lead-acid electrochemical cell, electric currents are composed of positive hydrogen ions (protons) flowing in one direction, and negative sulfate ions flowing in the other. Electric currents in sparks or plasma are flows of electrons as well as positive and negative ions. In ice and in certain solid electrolytes, the electric current is entirely composed of flowing ions. In a semiconductor it is sometimes useful to think of the current as due to the flow of positive "holes" (the mobile positive charge carriers that are places where the semiconductor crystal is missing a valence electron). This is the case in a p-type semiconductor.
The problem I have with this statement is the atoms of water are bound down in ice, nothing can move. Since ions tend to be the molecules this seems contradictory.
 

Thread Starter

jpanhalt

Joined Jan 18, 2008
11,087
I am sure most contributors to the thread from which that quote came ("delete my account " thread) will recognize it. It piqued my interest from the standpoint of definitions. That is, what is the most accepted definition of electrical current flow?

Is it restricted only to electrons in a conductor or does it include movement of holes in semiconductors and ions in other systems (e.g., electrophoresis and batteries)? Where do action potentials and nerve impulses fall?

Calling all pedantics. :D

John

Bill, We cross posted. John
 

Wendy

Joined Mar 24, 2008
23,429
I do not consider the hole movement anything but analogy, a way to understand what is happening inside a transistor that humans can make sense of. They are not particles, but the lack of a specific particle, the electron.

I get the feeling some folks think that electricity changes when it enters the body. I disagree with that point of view.

There are extremes in physics that doesn't involve electrons, but during everyday use, with one or two exceptions, we never see them.

The exceptions is battery chemistry and plating chemistry, which resemble in a lot of ways. In the end though, it is still electrons in and electrons out, which some complicated physics in between.

Current requires electrical charges to move, not neccessarily electrons. Could also be ions, positrons. Quarks also have charge, but do not occur isolated.
Positrons are a form of antimatter, wonder if the OP knew that? They are not naturally occuring particles either, but have to be manufactured on demand and used before they are consumed.

So ions is it. I'm interested in examples that might come up during this thread.
 

t06afre

Joined May 11, 2009
5,934
I get the feeling some folks think that electricity changes when it enters the body. I disagree with that point of view.
A simple way of measuring skin conductance is to use a low voltage DC source. Two electrodes are placed on the skin, and the resulting current is measured. The current that flow in the electrode leads is the same current that flow in the skin and body tissue.
 

beenthere

Joined Apr 20, 2004
15,819
So I wonder how the current got there.
From some years building electrofishing equipment, I can say that placing electrodes in impure water and applying a voltage will promote quite a bit of ionic conduction. I had to place a bit of protection circuitry in the control box to limit current at 15 amps.

It works in a vacuum, too. That is how mass spectrometry works. Or even isotopic separation as in the calutrons at Oak Ridge.

Any time an electrically unbalanced atom exists, an electric field will cause it to move.

In cells, there is a pump mechanism - http://en.wikipedia.org/wiki/Na+/K+-ATPase - that maintains a potential difference across a cell membrane. I have little experience with animal cells, but plant cells exhibit on the order of 50 mv potential difference intra - extracelular.
 
Last edited:

Wendy

Joined Mar 24, 2008
23,429
I used to work on helium leak testers, which is a dedicated mass spectrometer. Between the filament, the target, and the magnet I thought is was pretty obvious how they worked.

The quote is a bit out of context though, ultimately it is the wires that deliver the current.

From some years building electrofishing equipment, I can say that placing electrodes in impure water and applying a voltage will promote quite a bit of ionic conduction. I had to place a bit of protection circuitry in the control box to limit current at 15 amps.
As I understand it ionic conduction is still electron flow, as in the case of salt water. There are two mechanism happening as I understand it, one is the ions themselves moving to their respective electrodes, and the second is the electrons moving from ion to ion. Do I have it wrong?
 

studiot

Joined Nov 9, 2007
4,998
Without trying to delve deeper into what charge is

Physics theory as we know it recognises two polarities of charge viz positive and negative.

Charge is always associated with matter (ie particles with mass) As far as I know there are no known particles of zero rest mass with a charge.

Negative charges are associated with low mass particle, the most common being the electron.

Positive charges are associated with high mass charges the most common being the proton.

Current is an averaging term which describes the action of large numbers of charged particles over time.

So it is no suprise in our low energy world that current is associated with electrons not protons.

However most of the rest of the universe is made of stars. These are high energy worlds where the energy to move massive particles is in plentiful supply. Obviously electrons are also moved in stars but cosmic physics allows for proton currents in plasmas.

It is this asymetry of mass in charge carriers which makes one sort or the other more important depending upon the local environment.

Positive holes or negative holes are a convenient fiction or model. They have no physical reality and do not actually carry charge, they just simplify the charge accounting.
 
Top