Hi Eric,Might we suggest a 100x100 matrix of series and parallel feed? This will give you an impedance similar to a single diode, but you can feed it with a reasonable amount of voltage, less than 100 V, and only a few amps.
Hi Sarge:Hi Eric,
That's basically the idea by using the 24v switching power supplies; but keeping the voltage low enough to avoid any shock hazard.
Our OP seems to be a novice in electronics. I try to discourage "newbies" from experimenting with anything over around 45v due to the shock hazard.
The power supply I suggested is on sale, also what I felt was a reasonable compromise between his original idea (which would've wasted about 60% of the power applied), along with being a relatively safe voltage level to experiment with. Should the OP grow tired of watching 10,000 LEDs flash on and off, they'll still have a couple of decent power supplies they could use to power other projects.