The PICKIT 2 low pin count demo board come with a set of assembler lessons for the 16f690 you can find them here http://www.microchip.com/stellent/idcplg?IdcService=SS_GET_PAGE&nodeId=1406&dDocName=en023805 just scroll down the page.
PIC controllers are not very beginner friendly at all. So you must give you some time to learn.
PIC controllers are not very beginner friendly at all. So you must give you some time to learn.