I just bought MKII programmer form AVR and I want to program a ATMEGA 32 chip....I have been using arduino...now I want to go machine level...having more control on the u controller....please help me begin...all i want to do is...i think they call it bootloading...or not?? and then program it and use it independently...to begin with one LED control...help please...!!

 

Here is a good place to start if you are interested in assembly lanugage:
http://www.ladyada.net/learn/avr/