A two-state model of a hydrogen bond

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boks

Joined Oct 10, 2008
218
Suppose a hydrogen bond in water has an energy of about 2 kcal/mol. Suppose a "made" bond is the ground state in a two.state model and a "broken" bond is the excited state. At T = 300K, what fraction of hydrogen bonds are broken?
 

Boo

Joined Oct 27, 2009
40
Interesting, I've never come across this sort of question in my chemistry classes however, what equations were you taught in class? This is probably just a plug and play.
 

jpanhalt

Joined Jan 18, 2008
11,087
The solution, I believe, is reached in the same way you calculate the proportion of chair/boat configurations for 6-membered rings at various temperatures. Just look up equilibrium constant and Gibbs free energy.

John
 
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